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Theoretical study on complex f-f transition simulation of luminescence spectra of nanocrystalline X$_1$-Y$_2$SiO$_5$:Eu3$^+$

Abstract : Based on the electrostatic crystal-field model of M. Faucher, in which the induced electric dipoles of ligands are obtained from a set of self-consistent combined equations and the contributions from far ligands are considered, the crystal-field energy parameters of nanocrystalline X-1-Y2SiO5:Eu3+ at two sites both with C-1 symmetry are calculated by using related data of its crystal structure and physical properties, Moreover, we successfully extend the above model to calculate the transition intensities, therefore giving a computed simulation of luminescence spectroscopy consistent with the experimental one which we measured before, supporting the model and the data we adopted here
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http://hal.in2p3.fr/in2p3-00004172
Contributor : Suzanne Robert <>
Submitted on : Wednesday, March 15, 2000 - 11:05:12 AM
Last modification on : Wednesday, September 16, 2020 - 3:59:58 PM

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  • HAL Id : in2p3-00004172, version 1

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Changkui Duan, S. Xia, W. Zhang, M. Yin, J.C. Krupa. Theoretical study on complex f-f transition simulation of luminescence spectra of nanocrystalline X$_1$-Y$_2$SiO$_5$:Eu3$^+$. Journal of Alloys and Compounds, Elsevier, 1998, 277, pp.450-454. ⟨in2p3-00004172⟩

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