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Electro-oxidation of dihydroxymalonic acid on polycrystalline platinum electrode

Abstract : The electrooxidation of dihydroxymalonic acid (DHM) was investigated in neutral medium (0.1 M NaClO4) and dilute acidic medium (0.1 M HNO3) on polycrystalline platinum electrodes. Bulk electrolyses were performed mainly in diaphragmless cells, using suitable potential or current programmes (pulse electrolysis). The only carbon-bearing decomposition product formed proved to be CO2, with a current yield approaching 100% and zero-order kinetics with respect to the DHM concentration in solution. (C) 1999 Elsevier Science Ltd. All rights reserved.
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http://hal.in2p3.fr/in2p3-00023027
Contributor : Suzanne Robert <>
Submitted on : Wednesday, April 12, 2000 - 11:30:23 AM
Last modification on : Thursday, November 19, 2020 - 8:06:01 AM

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C. Le Naour, P. Moisy, S. Arpigny, C. Madic. Electro-oxidation of dihydroxymalonic acid on polycrystalline platinum electrode. Electrochimica Acta, Elsevier, 1999, 44, pp.3505-3512. ⟨in2p3-00023027⟩

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