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Neutron Diffraction Studies of U$_4$O$_9$: Comparison with EXAFS Results

Abstract : Conradson et al.1 have analyzed X-ray absorption fine-structure spectra of the UO$_2$-U$_4$O$_9$ system and concluded that oxygen atoms are incorporated in U$_4$O$_9$ as oxo groups with U-O distances in the range 1.72-1.76 Å. They also found that the uranium sublattice consists of an ordered portion and an additional 'spectroscopically silent' glassy portion. We have carried out studies of powdered U$_4$O$_9$ by neutron diffraction which contradict these conclusions from EXAFS measurements. Our analysis shows that there are no U-O bonds shorter than 2.2 Å and that U4O9 is crystallographically ordered with no evidence of a glassy structure.
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Contributor : Dominique Girod <>
Submitted on : Tuesday, October 17, 2006 - 1:37:53 PM
Last modification on : Monday, September 21, 2020 - 11:34:08 AM

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F. Garrido, A.C. Hannon, R.M. Ibberson, L. Nowicki, B.T.M. Willis. Neutron Diffraction Studies of U$_4$O$_9$: Comparison with EXAFS Results. Inorganic Chemistry, American Chemical Society, 2006, 45, pp.8408 -8413. ⟨10.1021/ic060964c⟩. ⟨in2p3-00107087⟩

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