The blazar PKS~2155-304 was the target of a multiwavelength campaign from June to October 2013 which widely improves our knowledge of its spectral energy distribution. This campaign involved the NuSTAR satellite (3-79 keV), the Fermi Large Area Telescope (LAT, 100~MeV-300~GeV) and the High Energy Stereoscopic System (H.E.S.S.) array phase II (with an energy threshold of few tens of GeV). While the observations with NuSTAR extend the X-ray spectrum to higher energies than before, H.E.S.S. phase II, together with the use of the LAT PASS 8, enhance the coverage of the γ-ray regime with an unprecedented precision. In this work, preliminary results from the multi-wavelength analysis are presented.