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The 5f $\rightarrow$ 6d absorption spectrum of Pa$^{4+}$/Cs$_2$ZrCl$_6$

Abstract : he 5f/sup 1/ to 6d/sup 1/ absorption spectrum of /sup 231/Pa/sup 4+/ diluted in a single crystal of Cs/sub 2/ZrCl/sub 6/ has been measured at 4.2 K. Three bands corresponding to the 6d( Gamma /sub 8g/, Gamma /sub 7g/ and Gamma '/sub 8g/) levels are assigned. Extensive vibronic structure has been observed for the lowest 5f to 6d transition and this structure is compared to that reported earlier for the 6d/sup 1/ to 5f/sup 1/ emission spectra in the same system.
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Contributor : Marie-Christine Blanchet Connect in order to contact the contributor
Submitted on : Monday, June 5, 2000 - 9:48:21 AM
Last modification on : Sunday, June 26, 2022 - 11:42:33 AM


  • HAL Id : in2p3-00004782, version 1



N. Edelstein, W.K. Kot, J. Krupa. The 5f $\rightarrow$ 6d absorption spectrum of Pa$^{4+}$/Cs$_2$ZrCl$_6$. Journal of Chemical Physics, American Institute of Physics, 1992, 96, pp.1-4. ⟨in2p3-00004782⟩



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