Synthesis and the Crystal Structure of Aqua-Dioxo-Nitrato-(2,2',6',2''-Terpyridine)-Neptunium(V)[NpO$_2$(NO$_3$)(Terpy)(H$_2$O)] - IN2P3 - Institut national de physique nucléaire et de physique des particules Access content directly
Journal Articles Crystallography Reports Year : 2003

Synthesis and the Crystal Structure of Aqua-Dioxo-Nitrato-(2,2',6',2''-Terpyridine)-Neptunium(V)[NpO$_2$(NO$_3$)(Terpy)(H$_2$O)]

N.A. Budantseva
  • Function : Author
G.B. Andreev
  • Function : Author
A.M. Fedoseev
  • Function : Author
M.Y. Antipin
  • Function : Author

Abstract

The crystal structure of the [NpO2(NO3)(Terpy)(H2O)] complex between pentavalent neptunium and 2,2,6,2-terpyridine is determined. The crystal data are as follows: a = 11.130(3) Å, b = 7.916(2) Å, c = 18.324(5) Å, = 100.873(6)°, V = 1585.5(8) Å3 , Z = 4, space group is P21/n, R = 0.044, and wR(F2) = 0.092. The coordination polyhedron of the Np atom is a pentagonal bipyramid whose equatorial plane includes three nitrogen atoms of the Terpy molecule and two oxygen atoms of the nitrate ion and the water molecule
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Dates and versions

in2p3-00012698 , version 1 (31-03-2003)

Identifiers

  • HAL Id : in2p3-00012698 , version 1

Cite

N.A. Budantseva, G.B. Andreev, A.M. Fedoseev, M.Y. Antipin, J.C. Krupa. Synthesis and the Crystal Structure of Aqua-Dioxo-Nitrato-(2,2',6',2''-Terpyridine)-Neptunium(V)[NpO$_2$(NO$_3$)(Terpy)(H$_2$O)]. Crystallography Reports, 2003, 48, pp.58-60. ⟨in2p3-00012698⟩
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