We classify the parity- and time-reversal-violating operators involving quark and gluon fields that have effective dimension six: the quark electric dipole moment, the quark and gluon chromo-electric dipole moments, and four four-quark operators. We construct the effective chiral Lagrangian with hadronic and electromagnetic interactions that originate from them and serves as the basis for calculations of low-energy observables. The form of the effective interactions depends on the chiral properties of these operators. We develop a power-counting scheme and calculate within this scheme, as an example, the parity- and time-reversal-violating pion-nucleon form factor. We also discuss the electric dipole moments of the nucleon and light nuclei.